Synthesis of linear and hyperbranched poly(silyl ester)s via cross-dehydrocoupling-based polymerization
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abstract
AB-type polymerizations based on cross-dehydrocoupling reactions for the preparation of poly(silyl ester)s with differing compositions and architecture were designed and accomplished to obtain the polymers with various hydrolytic stabilities and degradation profiles. Erosion processes of the resultant polymers were determined by AFM.