Crystal structure of the orange isomer of [(C6H5)3P]2[C2S2(CF3)2]RuCO
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The structure of the title compound has been determined by X-ray analysis. It is monoclinic:a = 10.147, b = 10.081, c = 38.627 Å, β = 102.27 °, Z = 4, P21/c. The structure was solved by standard methods and refined by least squares to a (conventional)R-factor of 4.7%. The Ru atom is in square-pyramidal configuration: the Ru-S distances (2.286, 2.336Å) are significantly different, but the Ru-P distances average to 2.389 Å. Comparisons are made with the violet isomer. © 1974 Plenum Publishing Company Limited.
author list (cited authors)
Bernal, I., Clearfield, A., & Ricci, J. S.