Crystal structure of the orange isomer of [(C6H5)3P]2[C2S2(CF3)2]RuCO Academic Article uri icon

abstract

  • The structure of the title compound has been determined by X-ray analysis. It is monoclinic:a = 10.147, b = 10.081, c = 38.627 Å, β = 102.27 °, Z = 4, P21/c. The structure was solved by standard methods and refined by least squares to a (conventional)R-factor of 4.7%. The Ru atom is in square-pyramidal configuration: the Ru-S distances (2.286, 2.336Å) are significantly different, but the Ru-P distances average to 2.389 Å. Comparisons are made with the violet isomer. © 1974 Plenum Publishing Company Limited.

author list (cited authors)

  • Bernal, I., Clearfield, A., & Ricci, J. S.

citation count

  • 18

publication date

  • January 1974