Irreversible Hydrolysis of PCP-Supported Rhenium(V) Acetates. Academic Article uri icon

abstract

  • Complexes (PCPR)Re(O)(OAc)2 [R = iPr (4a) and tBu (4b); PCP = 3-P,C,P-2,6-(R2PCH2)2C6H3] undergo unexpected irreversible hydrolysis to yield (PCPR)Re(O)(OAc)(OH) (3a/3b) and free AcOH. 3a and 3b are highly fluxional in solution, possibly via AcOH loss and the intermediacy of (PCPR)Re(O)2, which was isolated for R = tBu (5b).

published proceedings

  • Inorg Chem

altmetric score

  • 0.5

author list (cited authors)

  • Kosanovich, A. J., Shih, W., & Ozerov, O. V.

citation count

  • 6

complete list of authors

  • Kosanovich, Alex J||Shih, Wei-Chun||Ozerov, Oleg V

publication date

  • December 2017