Fullerene and TCNQ donor–acceptor crystals of octakis(dimethylamino) porphyrazine
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Reaction of octakis(dimethylamino)porphyrazine 1 with fullerene gives a crystalline 2:1 charge-transfer (CT) complex as a three-dimensional network of chains; in contrast, reaction of 1 with tetracyanoquinodimethane (TCNQ) gives a crystalline 1:1 charge transfer salt as one-dimensional integrated stacks.
author list (cited authors)
Eichhorn, D. M., Yang, S., Jarrell, W., Baumann, T. F., Beall, L. S., White, A., ... Hoffman, B. M.