Synthesis and characterisation of porphyrazinoctamine derivatives: X-ray crystallographic studies of [2,3,7,8,12,13,17,18-octakis(dibenzylamino)- porphyrazinato]magnesium( II ) and {2,3,7,8,12,13,17,18-octakis[allyl(benzyl)amino]- porphyrazinato} nickel( II ) Academic Article uri icon

abstract

  • 2,3-Bis(dibenzylamino)- and 2,3-bis[allyl(benzyl)amino]-2Z-butene-1,4- dinitriles are macrocyclised by reaction with magnesium propoxide in propanol to provide the corresponding (porphyrazinato)magnesium(II) derivatives, the structures of which are confirmed by X-ray crystallographic studies of the title magnesium and nickel(II) complexes; cyclisation of alternative diaminomaleonitrile derivatives gives the corresponding porphyrazinoctamines.

altmetric score

  • 6

author list (cited authors)

  • Mani, N. S., Beall, L. S., Miller, T., Anderson, O. P., Hope, H., Parkin, S. R., ... Hoffman, B. M.

citation count

  • 25

publication date

  • January 1994