Letter: Synthetic oxygen carrier. A dioxygen adduct of a manganese porphyrin. Academic Article

abstract

• In the past 5 years studies on the properties of cobalt(II) oxygen carriers1 have afforded an excellent opportunity to attack some of the central questions regarding biological oxygen carriers. More recently, it has been found that synthetic iron(II) systems can be reversibly oxygenated,2 offering further opportunities of characterizing transition metal-dioxygen interactions. We now have investigated the interaction of dioxygen with meso-tetraphenylporphyrin-(pyridine)manganese(II), Mn(TPP)(py), and report the first observations of reversible adduct formation between a manganese porphyrin and dioxygen. © 1975, American Chemical Society. All rights reserved.

authors

• Musser, Siegfried

published proceedings

• J Am Chem Soc

author list (cited authors)

• Weschler, C. J., Hoffman, B. M., & Basolo, F

citation count

• 67

complete list of authors

• Weschler, CJ||Hoffman, BM||Basolo, F

publication date

• September 1975

publisher

• American Chemical Society (ACS)  Publisher

published in

• Journal of the American Chemical Society  Journal

keywords

• Electron Spin Resonance Spectroscopy
• Manganese
• Oxidation-Reduction
• Oxygen
• Porphyrins

PubMed Central ID

• 170324

Digital Object Identifier (DOI)

• 10.1021/ja00851a043

start page

• 5278

end page

• 5280

volume

• 97

issue

• 18