Novel peripherally functionalized seco-porphyrazines: synthesis, characterization and spectroscopic evaluation Academic Article uri icon

abstract

  • Co-macrocyclizations of 2,3-dipropylmaleonitrile and 2,3-di-(4- (methoxycarbonyl)phenyl)maleonitrile, respectively, with N,N′-dibenzyl-N, N′-di-(11-tetrahydropyranyloxy-3,6,9-trioxo-undecyl))maleonitrile and N,N,N′,N′-tetramethylmaleonitrile were used to prepare derivatives of the 4,5-diamino-porphyrazine systems including the zinc(II) complexes. Subsequent oxidation of the macrocycles with potassium permanganate gave the corresponding seco-porphyrazines. These were shown to be efficient sensitizers for the production of singlet oxygen (ΦΔ=0.15-0.57) by the determination of their photophysical properties. © 2003 Published by Elsevier Ltd.

altmetric score

  • 3

author list (cited authors)

  • Sakellariou, E. G., Montalban, A. G., Beall, S. L., Henderson, D., Meunier, H. G., Phillips, D., ... Hoffman, B. M.

citation count

  • 35

publication date

  • November 2003