C(i) symmetric and non-centrosymmetric crystalline complexes of [60]fullerene with octakis(dimethylamino)porphyrazinato-copper(II) and - nickel(II) Academic Article uri icon

abstract

  • X-ray structural analysis of octakis(dimethylamino)porphyrazinato- metallo(II)ยท[60]fullerene complexes (M = Cu2+ and Ni2+) surprisingly revealed two totally different supramolecular structures, the first exhibiting a C(i) symmetric sandwich complex of two slightly dished porphyrazine units enclosing one fullerene sphere, the other featuring a noncentrosymmetric 1:1 complex with a strongly warped porphyrazine unit.

author list (cited authors)

  • Hochmuth, D. H., Michel, S., White, A., Williams, D. J., Barrett, A., & Hoffman, B. M.

publication date

  • January 2000