C(i) symmetric and non-centrosymmetric crystalline complexes of fullerene with octakis(dimethylamino)porphyrazinato-copper(II) and - nickel(II)
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X-ray structural analysis of octakis(dimethylamino)porphyrazinato- metallo(II)·fullerene complexes (M = Cu2+ and Ni2+) surprisingly revealed two totally different supramolecular structures, the first exhibiting a C(i) symmetric sandwich complex of two slightly dished porphyrazine units enclosing one fullerene sphere, the other featuring a noncentrosymmetric 1:1 complex with a strongly warped porphyrazine unit.
author list (cited authors)
Hochmuth, D. H., Michel, S., White, A., Williams, D. J., Barrett, A., & Hoffman, B. M.