An ambiphilic phosphine/H-bond donor ligand and its application to the gold mediated cyclization of propargylamides.
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We describe the synthesis of an ambiphilic phosphine/H-bond donor ligand featuring a trifluoroacetamide functionality, its coordination to gold(i) chloride, and its application as a self-activating catalyst for the cyclization of propargylamides.
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Sen, Srobona||Gabbaï, François P