Enforcing Ising-like magnetic anisotropy via trigonal distortion in the design of a W(v)-Co(ii) cyanide single-chain magnet. Academic Article

abstract

• A new octacyanotungstate(v) based single chain magnet {[(Tpm)Co(DMF)W(CN)8]2[Co(DMF)4]2DMF} n (1, Tpm = 1,1,1-trispyrazoylmethane), with an effective barrier of 39.7(3) cm-1 is reported. The Ising-like magnetic anisotropy of the chain originates from the nearly parallel local orientations of the Co(ii) ions with the source of the uniaxial magnetic anisotropy being a trigonal distortion of the octahedral environment with the fac-tridentate capping Tpm ligand.

authors

• Dunbar, Kim

published proceedings

• Chem Sci

author list (cited authors)

• Zhang, Y., Dolinar, B. S., Liu, S., Brown, A. J., Zhang, X., Wang, Z., & Dunbar, K. R.

citation count

• 32

complete list of authors

• Zhang, Yuan-Zhu||Dolinar, Brian S||Liu, Shihao||Brown, Andrew J||Zhang, Xuan||Wang, Zhao-Xi||Dunbar, Kim R

publication date

• January 2018

publisher

• Royal Society of Chemistry (RSC)  Publisher

published in

• Chemical Science  Journal

PubMed Central ID

• 29629079

Digital Object Identifier (DOI)

• 10.1039/c7sc02925j

start page

• 119

end page

• 124

volume

• 9

issue

• 1

URL

• http://dx.doi.org/10.1039/c7sc02925j