Synthesis of odd generation triazine dendrimers using a divergent, macromonomer approach.

abstract

• Using a macromonomer, first, third, and fifth generation triazine dendrimers can be prepared using a divergent approach. The nine-step process to the fifth generation target relies on an iterative two-reactions-per-generation strategy to yield the desired material in approximately 48% overall yield. This target displays 96 surface groups. NMR spectroscopy and mass spectrometry show that exceptionally narrow polydispersity is achieved using this strategy.

authors

• Perez, Lisa

published proceedings

• Org Lett

author list (cited authors)

• Lim, J., Mintzer, M. A., Perez, L. M., & Simanek, E. E.

citation count

• 35

complete list of authors

• Lim, Jongdoo||Mintzer, Meredith A||Perez, Lisa M||Simanek, Eric E

publication date

• March 2010

publisher

• American Chemical Society (ACS)  Publisher

published in

• Organic Letters  Journal

keywords

• Dendrimers
• Models, Molecular
• Molecular Structure
• Triazines

PubMed Central ID

• 20170155

Digital Object Identifier (DOI)

• 10.1021/ol902669g

start page

• 1148

end page

• 1151

volume

• 12

issue

• 6

URL

• http://dx.doi.org/10.1021/ol902669g