Gold Corroles as Near-IR Phosphors for Oxygen Sensing. Academic Article

abstract

• The triplet state of gold(III) corroles is exploited for optical oxygen sensing. We report intense phosphorescence for gold(III) corroles in the near-IR, an optical window that is ideal for tissue transparency. Moreover, the triplet excited-state emission exhibits significant changes in intensity and lifetime over the 0-160 Torr O2 pressure range. This renders these compounds sensitive at biologically relevant pressures and overcomes the spectral limitations of palladium and platinum porphyrins for oxygen sensing in biology.

authors

• Powers, David

published proceedings

• Inorg Chem

altmetric score

• 1.5

author list (cited authors)

• Lemon, C. M., Powers, D. C., Brothers, P. J., & Nocera, D. G.

citation count

• 38

complete list of authors

• Lemon, Christopher M||Powers, David C||Brothers, Penelope J||Nocera, Daniel G

publication date

• September 2017

publisher

• American Chemical Society (ACS)  Publisher

published in

• Inorganic Chemistry: including bioinorganic chemistry  Journal

keywords

• 0205 Optical Physics

PubMed Central ID

• 28872307

Digital Object Identifier (DOI)

• 10.1021/acs.inorgchem.7b01302

start page

• 10991

end page

• 10997

volume

• 56

issue

• 18