Gold Corroles as Near-IR Phosphors for Oxygen Sensing Academic Article uri icon

abstract

  • The triplet state of gold(III) corroles is exploited for optical oxygen sensing. We report intense phosphorescence for gold(III) corroles in the near-IR, an optical window that is ideal for tissue transparency. Moreover, the triplet excited-state emission exhibits significant changes in intensity and lifetime over the 0-160 Torr O2 pressure range. This renders these compounds sensitive at biologically relevant pressures and overcomes the spectral limitations of palladium and platinum porphyrins for oxygen sensing in biology.

author list (cited authors)

  • Lemon, C. M., Powers, D. C., Brothers, P. J., & Nocera, D. G.

publication date

  • January 1, 2017 11:11 AM