cis -Decalin oxidation as a stereochemical probe of in-MOF versus on-MOF catalysis
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Development of catalyst-controlled C-H hydroxylation could provide direct access to valuable synthetic targets, such as primary metabolites. Here, we report a new family of porous materials, comprised of 2-dimensional metalloporphyrin layers and flexible aliphatic linkers, and demonstrate C-H hydroxylation activity. We demonstrate that the stereochemistry of cis-decalin oxidation provides a useful tool for differentiating catalysis in from catalysis on porous materials, which is critical to leveraging the potential of porous materials for catalyst-controlled oxidation chemistry.
author list (cited authors)
Cardenal, A. D., Jeong Park, H., Chalker, C. J., Ortiz, K. G., & Powers, D. C.
complete list of authors
Cardenal, Ashley D||Jeong Park, Hye||Chalker, Cody J||Ortiz, Kacey G||Powers, David C