Inserting sulfur donor ligands in axial positions of an extended trinickel chain Academic Article

abstract

• The stoichiometric reaction of [Ni3(dpa)4(CH3CN)2](PF6)2 (1) with NaSPh in dichloromethane, affords the linear trinuclear complex Ni3(dpa)4(SPh)2 (2) in good yield and excellent purity (dpa is the anion of 2,2-dipyridylamine). This compound represents the first extended metal atom chain (EMAC) with sulfur-containing axial ligands and was characterized by X-ray single-crystal diffraction, elemental analysis, ESI-MS, UV-vis spectrum and magnetic susceptibility measurements. 2007 Elsevier B.V. All rights reserved.

authors

• Wang, Qingsheng

published proceedings

• INORGANIC CHEMISTRY COMMUNICATIONS

author list (cited authors)

• Cotton, F. A., Murillo, C. A., & Wang, Q.

citation count

• 11

complete list of authors

• Cotton, F Albert||Murillo, Carlos A||Wang, Qingsheng

publication date

• September 2007

publisher

• Elsevier  Publisher

published in

• Inorganic Chemistry Communications  Journal

keywords

• Extended Metal Atom Chains (emacs)
• Magnetic Susceptibility
• Sulfur Donor Ligand
• Trinickel Complex
• X-ray Crystallography

Digital Object Identifier (DOI)

• 10.1016/j.inoche.2007.06.001

start page

• 1088

end page

• 1090

volume

• 10

issue

• 9

URL

• http://dx.doi.org/10.1016/j.inoche.2007.06.001