Zirconium-metalloporphyrin PCN-222: mesoporous metal-organic frameworks with ultrahigh stability as biomimetic catalysts. Academic Article uri icon

abstract

  • Biomimetic MOF: Extremely stable MOFs with different open metal sites and ultra-large 1D channels, PCN-222 (Fe, Mn, Co, Ni, Cu, and Zn), have been assembled with eight-connected Zr6 clusters and redox-active metalloporphyrin motifs. PCN-222(Fe) shows peroxidase-like activity in aqueous solution, exhibiting highly effective biomimetic oxidation on a number of substrates. Copyright 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

published proceedings

  • Angew Chem Int Ed Engl

altmetric score

  • 10.1

author list (cited authors)

  • Feng, D., Gu, Z., Li, J., Jiang, H., Wei, Z., & Zhou, H.

citation count

  • 1302

complete list of authors

  • Feng, Dawei||Gu, Zhi-Yuan||Li, Jian-Rong||Jiang, Hai-Long||Wei, Zhangwen||Zhou, Hong-Cai

publication date

  • October 2012

publisher