Pore surface engineering with controlled loadings of functional groups via click chemistry in highly stable metal-organic frameworks. Academic Article

abstract

• Reactions of ZrCl(4) and single or mixed linear dicarboxylic acids bearing methyl or azide groups lead to highly stable isoreticular metal-organic frameworks (MOFs) with content-tunable, accessible, reactive azide groups inside the large pores. These Zr-based MOFs offer an ideal platform for pore surface engineering by anchoring various functional groups with controlled loadings onto the pore walls via the click reaction, endowing the MOFs with tailor-made interfaces. Significantly, the framework and crystallinity of the functionalized MOFs are well-retained, and the engineered pore surfaces have been demonstrated to be readily accessible, thus providing more opportunities for powerful and broad applications of MOFs.

authors

• Zhou, Hongcai

published proceedings

• J Am Chem Soc

altmetric score

• 6.25

author list (cited authors)

• Jiang, H., Feng, D., Liu, T., Li, J., & Zhou, H.

citation count

• 322

complete list of authors

• Jiang, Hai-Long||Feng, Dawei||Liu, Tian-Fu||Li, Jian-Rong||Zhou, Hong-Cai

publication date

• September 2012

publisher

• American Chemical Society (ACS)  Publisher

published in

• Journal of the American Chemical Society  Journal

keywords

• Chlorides
• Click Chemistry
• Dicarboxylic Acids
• Models, Molecular
• Molecular Structure
• Organometallic Compounds
• Surface Properties
• Zinc Compounds

PubMed Central ID

• 22906023

Digital Object Identifier (DOI)

• 10.1021/ja3063919

start page

• 14690

end page

• 14693

volume

• 134

issue

• 36

URL

• http://dx.doi.org/10.1021/ja3063919