Linker extension through hard-soft selective metal coordination for the construction of a non-rigid metal-organic framework
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abstract
A metal-organic framework (MOF) has been obtained by using a linker extension strategy. Three di-anions of 4-(3,5-dimethyl-1H-pyrazol-4-yl)-benzoic acid coordinate to three Cu(I) ions forming an extended trigonal planar ligand, which links three di-copper paddlewheel units giving rise to a Pt 3O4 net. 2013 Science China Press and Springer-Verlag Berlin Heidelberg.