Pressure-responsive curvature change of a "rigid" geodesic ligand in a (3,24)-connected mesoporous metal-organic framework. Academic Article uri icon

abstract

  • A (3,24)-connected mesoporous metal-organic framework, PCN-69, was synthesized by linking a hexatopic ligand btti with dicopper paddlewheel clusters. This material has rigid connectivity but a flexible framework, which has been attributed to a curvature change of the ligand.

published proceedings

  • Inorg Chem

altmetric score

  • 3

author list (cited authors)

  • Yuan, D., Zhao, D., & Zhou, H.

citation count

  • 68

complete list of authors

  • Yuan, Daqiang||Zhao, Dan||Zhou, Hong-Cai

publication date

  • November 2011