Pressure-Responsive Curvature Change of a “Rigid” Geodesic Ligand in a (3,24)-Connected Mesoporous Metal–Organic Framework Academic Article uri icon

abstract

  • A (3,24)-connected mesoporous metal-organic framework, PCN-69, was synthesized by linking a hexatopic ligand btti with dicopper paddlewheel clusters. This material has rigid connectivity but a flexible framework, which has been attributed to a curvature change of the ligand.

author list (cited authors)

  • Yuan, D., Zhao, D., & Zhou, H.

publication date

  • January 1, 2011 11:11 AM