Pressure-responsive curvature change of a "rigid" geodesic ligand in a (3,24)-connected mesoporous metal-organic framework.

abstract

• A (3,24)-connected mesoporous metal-organic framework, PCN-69, was synthesized by linking a hexatopic ligand btti with dicopper paddlewheel clusters. This material has rigid connectivity but a flexible framework, which has been attributed to a curvature change of the ligand.

authors

• Zhou, Hong-Cai

published proceedings

• Inorg Chem

altmetric score

• 3

author list (cited authors)

• Yuan, D., Zhao, D., & Zhou, H.

citation count

• 68

complete list of authors

• Yuan, Daqiang||Zhao, Dan||Zhou, Hong-Cai

publication date

• November 2011

publisher

• American Chemical Society (ACS)  Publisher

published in

• Inorganic Chemistry  Journal

keywords

• 0302 Inorganic Chemistry

PubMed Central ID

• 21942344

Digital Object Identifier (DOI)

• 10.1021/ic201744n

start page

• 10528

end page

• 10530

volume

• 50

issue

• 21

URL

• http://dx.doi.org/10.1021/ic201744n