A highly stable zeotype mesoporous zirconium metal-organic framework with ultralarge pores. Academic Article

abstract

• Through topological rationalization, a zeotype mesoporous Zr-containing metal-organic framework (MOF), namely PCN-777, has been designed and synthesized. PCN-777 exhibits the largest cage size of 3.8nm and the highest pore volume of 2.8cm(3) g(-1) among reported Zr-MOFs. Moreover, PCN-777 shows excellent stability in aqueous environments, which makes it an ideal candidate as a support to incorporate different functional moieties. Through facile internal surface modification, the interaction between PCN-777 and different guests can be varied to realize efficient immobilization.

authors

• Zhou, Hongcai

published proceedings

• Angew Chem Int Ed Engl

altmetric score

• 0.25

author list (cited authors)

• Feng, D., Wang, K., Su, J., Liu, T., Park, J., Wei, Z., ... Zhou, H.

citation count

• 232

complete list of authors

• Feng, Dawei||Wang, Kecheng||Su, Jie||Liu, Tian-Fu||Park, Jihye||Wei, Zhangwen||Bosch, Mathieu||Yakovenko, Andrey||Zou, Xiaodong||Zhou, Hong-Cai

publication date

• January 2015

publisher

• Wiley  Publisher

published in

• Angewandte Chemie International Edition  Journal

keywords

• Carboxylate Ligands
• Host-guest Systems
• Mesoporous Materials
• Metal-organic Frameworks
• Zirconium

PubMed Central ID

• 25385329

Digital Object Identifier (DOI)

• 10.1002/anie.201409334

start page

• 149

end page

• 154

volume

• 54

issue

• 1

URL

• http://dx.doi.org/10.1002/anie.201409334