Surface functionalization of metal–organic polyhedron for homogeneous cyclopropanation catalysis Academic Article uri icon

abstract

  • A super-paddlewheel (comprised of two paddlewheels) metal-organic polyhedron (MOP) containing surface hydroxyl groups was synthesized and characterized. Condensation reactions with linear alkyl anhydrides lead to new MOPs with enhanced solubility. As a result, the surface-modified MOP 4 was demonstrated as a homogeneous Lewis-acid catalyst.

altmetric score

  • 3

author list (cited authors)

  • Lu, W., Yuan, D., Yakovenko, A., & Zhou, H.

citation count

  • 72

publication date

  • March 2011