Surface functionalization of metal-organic polyhedron for homogeneous cyclopropanation catalysis. Academic Article

abstract

• A super-paddlewheel (comprised of two paddlewheels) metal-organic polyhedron (MOP) containing surface hydroxyl groups was synthesized and characterized. Condensation reactions with linear alkyl anhydrides lead to new MOPs with enhanced solubility. As a result, the surface-modified MOP 4 was demonstrated as a homogeneous Lewis-acid catalyst.

authors

• Zhou, Hongcai

published proceedings

• Chem Commun (Camb)

altmetric score

• 3

author list (cited authors)

• Lu, W., Yuan, D., Yakovenko, A., & Zhou, H.

citation count

• 91

complete list of authors

• Lu, Weigang||Yuan, Daqiang||Yakovenko, Andrey||Zhou, Hong-Cai

publication date

• May 2011

publisher

• Royal Society of Chemistry (RSC)  Publisher

published in

• Chemical Communications  Journal

keywords

• Alkylation
• Anhydrides
• Catalysis
• Copper
• Cyclopropanes
• Hydrocarbons, Alicyclic
• Hydroxylation
• Metals
• Molecular Conformation
• Solubility
• Surface Properties

PubMed Central ID

• 21423990

Digital Object Identifier (DOI)

• 10.1039/c1cc00030f

start page

• 4968

end page

• 4970

volume

• 47

issue

• 17