Flexible Zirconium MOF as the Crystalline Sponge for Coordinative Alignment of Dicarboxylates.

abstract

• Because of their permanent porosity and unparalleled structural diversities, flexible metal-organic frameworks (MOFs) are promising and highly desirable in host-guest chemistry. In this work, we employed a flexible Zr-MOF system, namely PCN-700 species, as the crystalline sponge for guest inclusion. A family of linear dicarboxylate ligands was adsorbed in the void space of PCN-700, which were subsequently confirmed by crystallographic observation. The stretching degree of the PCN-700 series was varied by means of dicarboxylate encapsulation through coordinative alignment.

authors

• Zhou, Hong-Cai

published proceedings

• ACS Appl Mater Interfaces

author list (cited authors)

• Qin, J., Yuan, S., Alsalme, A., & Zhou, H.

citation count

• 45

complete list of authors

• Qin, Jun-Sheng||Yuan, Shuai||Alsalme, Ali||Zhou, Hong-Cai

publication date

• October 2017

publisher

• American Chemical Society (ACS)  Publisher

published in

• ACS Applied Materials & Interfaces  Journal

keywords

• Coordination Bond
• Crystalline Sponge
• Flexibility
• Guest Encapsulation
• Metal−organic Framework (mof)
• Zirconium

PubMed Central ID

• 28165703

Digital Object Identifier (DOI)

• 10.1021/acsami.6b16264

start page

• 33408

end page

• 33412

volume

• 9

issue

• 39

URL

• http://dx.doi.org/10.1021/acsami.6b16264