Control over Interpenetration in Lanthanide−Organic Frameworks: Synthetic Strategy and Gas-Adsorption Properties Academic Article uri icon

abstract

  • Two isostructural lanthanide-organic frameworks (1 and 2) with 2-fold interpenetrating nets have been synthesized based on 1,4-benzenedicarboxylic acid (H(2)BDC). By application of an organic ligand with hindrance groups and a terminal chelating ligand to replace BDC and coordinated solvates, interpenetration has been effectively controlled. The gas-sorption properties of the noninterpenetrating net have been studied.

author list (cited authors)

  • He, H., Yuan, D., Ma, H., Sun, D., Zhang, G., & Zhou, H.

publication date

  • January 1, 2010 11:11 AM