Highly stable porous polymer networks with exceptionally high gas-uptake capacities.
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abstract
Highly stable porous polymer networks (PPNs) are synthesized through Yamamoto homocoupling reaction between tetrahedral monomers. Among those polymers, PPN-4 shows exceptionally high Langmuir surface area of 10063 m 2 g -1 (SA BET: 6461 m 2 g -1). It also exhibits ultra-high hydrogen (158 mg g -1), methane (389 mg g -1), and carbon dioxide (2121 mg g -1) storage capacities. These properties make it a perfect adsorbent for clean energy applications. 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.