A large-surface-area boracite-network-topology porous MOF constructed from a conjugated ligand exhibiting a high hydrogen uptake capacity. Academic Article uri icon

abstract

  • A new porous metal-organic framework, PCN-20 with a twisted boracite net topology, was constructed based on a highly conjugated planar tricarboxylate ligand; PCN-20 possesses a large Langmuir surface area of over 4200 m(2)/g as well as demonstrates a high hydrogen uptake capacity of 6.2 wt % at 77 K and 50 bar.

published proceedings

  • Inorg Chem

author list (cited authors)

  • Wang, X., Ma, S., Yuan, D., Yoon, J. W., Hwang, Y. K., Chang, J., ... Zhou, H.

citation count

  • 65

complete list of authors

  • Wang, Xi-Sen||Ma, Shengqian||Yuan, Daqiang||Yoon, Ji Woong||Hwang, Young Kyu||Chang, Jong-San||Wang, Xiaoping||Jørgensen, Mads Ry||Chen, Yu-Sheng||Zhou, Hong-Cai

publication date

  • August 2009