Synthesis and characterization of a novel layered titanium phosphate Academic Article

abstract

• A novel metastable layered titanium phosphate has been synthesized by the treatment of layered titanates (Na2Ti3O7 and Na4Ti9O20) with 12 M phosphoric acid solution at 120150 C. Based on the data of 31P MAS NMR and IR spectroscopy, x-ray powder diffraction, and thermal and elemental analysis, the formula Ti2O3(H2PO4)2 2H2O was assigned to the novel compound. The layered nature of the compound was confirmed from n-alkylamine intercalation and the ion exchange behavior toward alkali, alkaline earth, and some transition metal ions.

authors

• Clearfield, Abraham

published proceedings

• JOURNAL OF MATERIALS RESEARCH

author list (cited authors)

• Bortun, A. I., Bortun, L., Clearfield, A., VillaGarcia, M. A., Garcia, J. R., & Rodriguez, J.

citation count

• 54

complete list of authors

• Bortun, AI||Bortun, L||Clearfield, A||VillaGarcia, MA||Garcia, JR||Rodriguez, J

publication date

• October 1996

publisher

• Springer Nature  Publisher

published in

• Journal of Materials Research  Journal

keywords

• 40 Engineering
• 4016 Materials Engineering
• 4017 Mechanical Engineering
• 51 Physical Sciences
• 5104 Condensed Matter Physics

Digital Object Identifier (DOI)

• 10.1557/JMR.1996.0314

start page

• 2490

end page

• 2498

volume

• 11

issue

• 10

URL

• http://dx.doi.org/10.1557/jmr.1996.0314