Synthesis and characterization of a novel layered titanium phosphate Academic Article uri icon

abstract

  • A novel metastable layered titanium phosphate has been synthesized by the treatment of layered titanates (Na2Ti3O7 and Na4Ti9O20) with 12 M phosphoric acid solution at 120150 C. Based on the data of 31P MAS NMR and IR spectroscopy, x-ray powder diffraction, and thermal and elemental analysis, the formula Ti2O3(H2PO4)2 2H2O was assigned to the novel compound. The layered nature of the compound was confirmed from n-alkylamine intercalation and the ion exchange behavior toward alkali, alkaline earth, and some transition metal ions.

published proceedings

  • JOURNAL OF MATERIALS RESEARCH

author list (cited authors)

  • Bortun, A. I., Bortun, L., Clearfield, A., VillaGarcia, M. A., Garcia, J. R., & Rodriguez, J.

citation count

  • 54

complete list of authors

  • Bortun, Anatoly I||Bortun, Lyudmila||Clearfield, Abraham||Villa-García, María A||García, José R||Rodríguez, Julio

publication date

  • October 1996