Modification and intercalation of layered zirconium phosphates: a solid‐state NMR monitoring Academic Article uri icon

abstract

  • Several layered zirconium phosphates treated with Zr(IV) ions, modified by monomethoxy-polyethyleneglycol-monophosphate and intercalated with doxorubicin hydrochloride have been studied by solid-state MAS NMR techniques. The organic components of the phosphates have been characterized by the 13 C{1 H} CP MAS NMR spectra compared with those of initial compounds. The multinuclear NMR monitoring has provided to establish structure and covalent attachment of organic/inorganic moieties to the surface and interlayer spaces of the phosphates. The MAS NMR experiments including kinetics of proton-phosphorus cross polarization have resulted in an unusual structure of zirconium phosphate 6 combining decoration of the phosphate surface by polymer units and their partial intercalation into the interlayer space. Copyright © 2016 John Wiley & Sons, Ltd.

altmetric score

  • 1.5

author list (cited authors)

  • Bakhmutov, V. I., Kan, Y., Sheikh, J. A., González‐Villegas, J., Colón, J. L., & Clearfield, A.

citation count

  • 6

publication date

  • January 2017

publisher