Disulfido iron-manganese carbonyl cluster complexes:: Synthesis, structure, bonding and properties of the radical CpFeMn2(CO)7(3-S2)2
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abstract
Two new compounds CpFeMn2(CO)7(3-S2)2 (2) and Cp3Fe3Mn(CO)4(3-S 2)2(3-S) (3) were obtained by the treatment of [CpFeMn(CO)5(3-S2)]2 (1) with CO at room temperature in the presence of room light.