Crystallographic evidence of a base-free uranium(IV) terminal oxo species. Academic Article uri icon

abstract

  • The uranium(IV) terminal oxo species Tp*(2)U(O) has been synthesized by oxygen-atom transfer from pyridine-N-oxide to Tp*(2)U(2,2'-bipyridine), a trivalent uranium species with a monoanionic bipyridine ligand. Full characterization of the oxo species using (1)H NMR and IR spectroscopies, X-ray crystallography, and computational studies was performed.

published proceedings

  • Inorg Chem

author list (cited authors)

  • Kraft, S. J., Walensky, J., Fanwick, P. E., Hall, M. B., & Bart, S. C.

citation count

  • 68

complete list of authors

  • Kraft, Steven J||Walensky, Justin||Fanwick, Phillip E||Hall, Michael B||Bart, Suzanne C

publication date

  • September 2010