REACTIONS OF SILICA-ALUMINA SUPPORTED BENZYLIDYNENONACARBONYLTRICOBALT UNDER HYDROGEN, CARBON-MONOXIDE, AND SYNTHESIS GAS Academic Article

abstract

• The cluster C6H5CCo3(CO)9, containing a capping C6H5C= group, was supported on SiO2-Al2O3by wet impregnation or dry mixing. The fate of the capping group was traced by monitoring the gas-phase liberation of cyclic C6 and C7 hydrocarbons under CO, H2, and CO/H2 atmospheres. For the wet-impregnated material, the presence of CO favors the cyclic C6 product (C-C bond cleavage) and inhibits hydrogenolysis of the capping group (C-Co bond cleavage). A model accounting for this behavior proposes that CO inserts between the C-Co bond of intact surface clusters. 1985, American Chemical Society. All rights reserved.

authors

• Hall, Michael

published proceedings

• ORGANOMETALLICS

author list (cited authors)

• MEYERS, G. F., & HALL, M. B.

citation count

• 9

complete list of authors

• MEYERS, GF||HALL, MB

publication date

• October 1985

publisher

• American Chemical Society (ACS)  Publisher

published in

• Organometallics  Journal

Digital Object Identifier (DOI)

• 10.1021/om00129a015

start page

• 1770

end page

• 1775

volume

• 4

issue

• 10

URL

• http://dx.doi.org/10.1021/om00129a015