Bonding and Reactivity in the Electronically Unsaturated Hydrogen-Bridged Dimer [Ru₃(CO)₈(₃-CMe)(-H)₂(₃-H)]₂ Academic Article

abstract

• The electronically unsaturated complex [Ru 3(CO) 8-( 3-CMe)(-H) 2( 3-H)] 2 (1), viewed as a dimer of the 46-electron fragment Ru 3(CO) 8( 3-CMe)(-H) 3, is held together by delocalized bonding involving two triply bridging hydride ligands. Compound 1 exhibits a dynamic activity in solution that equilibrates two of the three types of hydride ligands. Compound 1 reacts with 1,1- bis(diphenylphosphino) methane to form the macrocyclic complex [Ru 3(CO) 7-( 3-CMe)(-H) 3] 2(-dppm) 2 (3). 2011 American Chemical Society.

authors

• Hall, Michael

published proceedings

• ORGANOMETALLICS

altmetric score

• 1

author list (cited authors)

• Adams, R. D., Kan, Y., Zhang, Q., Hall, M. B., & Trufan, E.

citation count

• 5

complete list of authors

• Adams, Richard D||Kan, Yuwei||Zhang, Qiang||Hall, Michael B||Trufan, Eszter

publication date

• January 2012

publisher

• American Chemical Society (ACS)  Publisher

published in

• Organometallics  Journal

keywords

• 34 Chemical Sciences
• 3402 Inorganic Chemistry

Digital Object Identifier (DOI)

• 10.1021/om2012375

start page

• 50

end page

• 53

volume

• 31

issue

• 1

URL

• http://dx.doi.org/10.1021/om2012375