Reversible photoreduction of Cu(ii)-coumarin metal-organic polyhedra. Academic Article

abstract

• We report a new approach for photoinduced reduction of Cu2+ that will enrich the structural diversity of coordination complexes and be a valuable contributor to the development of Cu+/Cu0-based catalysts. To realize controlled Cu2+ reduction, coumarin as a triplet quencher of excited benzophenone was tethered to Cu(ii)-metal-organic polyhedra (MOPs). The photoinduced catalytic activity of the coumarin-MOPs was also examined in a Cu(i)-catalyzed azide-alkyne cycloaddition (CuAAC).

authors

• Zhou, Hongcai

published proceedings

• Chem Commun (Camb)

author list (cited authors)

• Bae, J., Baek, K., Yuan, D., Kim, W., Kim, K., Zhou, H., & Park, J.

citation count

• 12

complete list of authors

• Bae, Jaeyeon||Baek, Kangkyun||Yuan, Daqiang||Kim, Wooram||Kim, Kimoon||Zhou, Hong-Cai||Park, Jinhee

publication date

• August 2017

publisher

• Royal Society of Chemistry (RSC)  Publisher

published in

• Chemical Communications  Journal

PubMed Central ID

• 28766591

Digital Object Identifier (DOI)

• 10.1039/c7cc04799a

start page

• 9250

end page

• 9253

volume

• 53

issue

• 66

URL

• http://dx.doi.org/10.1039/c7cc04799a