F-19 and Hg-199 NMR of trimeric perfluoro-ortho-phenylenemercury Academic Article uri icon

abstract

  • 19 F and 199 Hg high-resolution solution NMR spectra were acquired for cyclic trimeric perfluoro-ortho-phenylenemercury. Even with the high superconducting magnetic fields currently available, the 19 F spectrum was not interpretable with a simple first-order analysis. Spectroscopic parameters for chemical shift and scalar coupling interactions in the NMR spectra were extracted from four- and five-spin simulations. Differential line widths in the 19 F spectrum result from scalar coupling to the 199 Hg. 2006 Elsevier B.V. All rights reserved.

published proceedings

  • JOURNAL OF MOLECULAR STRUCTURE

author list (cited authors)

  • Taylor, R. E., & Gabbai, F. P.

citation count

  • 6

complete list of authors

  • Taylor, RE||Gabbaii, Francois P

publication date

  • August 2007