¹⁹F and ¹⁹⁹Hg NMR of trimeric perfluoro-ortho-phenylenemercury

abstract

• 19 F and 199 Hg high-resolution solution NMR spectra were acquired for cyclic trimeric perfluoro-ortho-phenylenemercury. Even with the high superconducting magnetic fields currently available, the 19 F spectrum was not interpretable with a simple first-order analysis. Spectroscopic parameters for chemical shift and scalar coupling interactions in the NMR spectra were extracted from four- and five-spin simulations. Differential line widths in the 19 F spectrum result from scalar coupling to the 199 Hg. 2006 Elsevier B.V. All rights reserved.

authors

• Gabbai, Francois

published proceedings

• JOURNAL OF MOLECULAR STRUCTURE

author list (cited authors)

• Taylor, R. E., & Gabbai, F. P.

citation count

• 6

complete list of authors

• Taylor, RE||Gabbaii, Francois P

publication date

• August 2007

publisher

• Elsevier  Publisher

keywords

• F-19 Nmr
• Hg-199 Nmr
• Lewis Acid
• Mercury
• NMR
• Strong Scalar Coupling
• Trimeric Perfluoro-ortho-phenylenemercury

Digital Object Identifier (DOI)

• 10.1016/j.molstruc.2006.10.025

start page

• 28

end page

• 32

volume

• 839

issue

• 1-3

URL

• http://dx.doi.org/10.1016/j.molstruc.2006.10.025