LASER-ION BEAM PHOTODISSOCIATION STUDIES OF C3H3BR+ AND C3H3CL+

abstract

• The photodissociation reactions of the 3-chloro-1-propyne and 3-bromo-1-propyne radical ions have been studied using a laser-ion beam photodissociation apparatus. The photodissociation spectra reflect the spin-orbit splitting of the ground electronic states of the ion. The C3H3Cl+ and C3H3Br+ systems dissociate to yield exclusively C3H3+ in the total energy range 12.9-13.7 eV. This reaction channel is assigned to a direct dissociation from a repulsive electronic state. Finally, comparisons between the unimolecular and the photofragment kinetic energy release values suggest a propargyl structure for the C3H3+ photofragment ion. 1985.

authors

• Russell, David

published proceedings

• INTERNATIONAL JOURNAL OF MASS SPECTROMETRY AND ION PROCESSES

author list (cited authors)

• KRAILLER, R. E., & RUSSELL, D. H.

citation count

• 9

complete list of authors

• KRAILLER, RE||RUSSELL, DH

publication date

• June 1985

publisher

• Elsevier  Publisher

published in

• International Journal of Mass Spectrometry and Ion Processes  Journal

Digital Object Identifier (DOI)

• 10.1016/0168-1176(85)80007-0

start page

• 339

end page

• 351

volume

• 66

issue

• 3

URL

• http://dx.doi.org/10.1016/0168-1176(85)80007-0