Launching a particle on a ring: b2u-->ke2g ionization of C6F6.
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Evidence is presented demonstrating that an electron launched into the continuum is trapped in an unprecedented quasibound state, namely, one that extends through the backbone of the six-member carbon ring of C6F6. The mode specificity of the vibrational sensitivity to the electron trapping provides an experimental signature for this phenomenon, while adiabatic static model-exchange scattering calculations are used to map the wave function, which corroborate the interpretation.
author list (cited authors)
Das, A., Poliakoff, E. D., Lucchese, R. R., & Bozek, J. D.
complete list of authors
Das, Aloke||Poliakoff, ED||Lucchese, RR||Bozek, John D