Excitation of the symmetry forbidden bending mode in molecular photoionization Academic Article

abstract

• Excitation of the symmetry forbidden bending mode in molecular photoionization of CO2 had been investigated. The v+=(0,1,0)/v+=(0,0,0) intesity ratio was determined by detecting disperesed fluorescene from the electronically excited photoions. the results showed deviations in the wide energy range of 18 to 190 eV. Experimental results were interpreted by theoretical framework and Schwinger variational calculations were performed. Calculations showed continuum electron responsible for the observation of excited bending mode and its energy dependence.

authors

• Lucchese, Robert

published proceedings

• JOURNAL OF CHEMICAL PHYSICS

author list (cited authors)

• Miller, J. S., Poliakoff, E. D., Miller, T. F., Natalense, A., & Lucchese, R. R.

citation count

• 24

complete list of authors

• Miller, JS||Poliakoff, ED||Miller, TF||Natalense, APP||Lucchese, RR

publication date

• March 2001

publisher

• AIP Publishing  Publisher

published in

• Journal of Chemical Physics  Journal

keywords

• 34 Chemical Sciences
• 3406 Physical Chemistry
• 51 Physical Sciences
• 5102 Atomic, Molecular And Optical Physics

Digital Object Identifier (DOI)

• 10.1063/1.1349090

start page

• 4496

end page

• 4504

volume

• 114

issue

• 10

URL

• http://dx.doi.org/10.1063/1.1349090