Strong Ferromagnetic Exchange Coupling Mediated by a Bridging Tetrazine Radical in a Dinuclear Nickel Complex. Academic Article uri icon

abstract

  • The radical bridged compound [(Ni(TPMA))2--bmtz-](BF4)33CH3CN (bmtz = 3,6-bis(2'-pyrimidyl)-1,2,4,5-tetrazine, TPMA = tris(2-pyridylmethyl)amine) exhibits strong ferromagnetic exchange between the S = 1 NiII centers and the bridging S = 1/2 bmtz radical with J = 96 5 cm-1 (-2JNi-radSNiSrad). DFT calculations support the existence of strong ferromagnetic exchange.

published proceedings

  • Inorg Chem

altmetric score

  • 1

author list (cited authors)

  • Woods, T. J., Stout, H. D., Dolinar, B. S., Vignesh, K. R., Ballesteros-Rivas, M. F., Achim, C., & Dunbar, K. R.

citation count

  • 24

complete list of authors

  • Woods, Toby J||Stout, Heather D||Dolinar, Brian S||Vignesh, Kuduva R||Ballesteros-Rivas, Maria F||Achim, Catalina||Dunbar, Kim R

publication date

  • October 2017