Synthesis of 1,8-diborylnaphthalenes by the ring-opening reaction of a new anionic boron-bridged naphthalene derivative
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abstract
Synthesis of 1,8-diborylnaphthalenes by the ring-opening reaction of a new anionic boron-bridged naphthalene derivative was studied. The reaction of the derivative with dimesitylboron fluoride led to the formation of a precipitate that can be recrystallized. The NMR spectroscopy revealed the existence of a symmetrically substituted naphthalene ring and a unique mesityl environment.