Heterometallic molecular squares and polymers based on self-assembly reactions of multiply bonded dirhenium complexes Academic Article

abstract

• Self-assembly reactions of the triply-bonded dirhenium complex cis-[Re2Cl2(dppm)2(O2CC5H4N-4)2] with cis-protected PtIIand ZnIIprecursors have produced heterometallic squares. Analogous reactions with Ag(O3SCF3), cis-[Re2-Cl4(O2CCH3)2(H2O)2] and [Rh2(O2CCH3)4] have yielded mixed-metal polymeric structures. These results demonstrate that the isonicotinate ligand is useful for accessing heterometallic structures involving metal-metal bonded complexes. Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2004.

authors

• Dunbar, Kim

published proceedings

• EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

author list (cited authors)

• Bera, J. K., Bacsa, J., Smucker, B. W., & Dunbar, K. R.

citation count

• 25

complete list of authors

• Bera, JK||Bacsa, J||Smucker, BW||Dunbar, KR

publication date

• January 2004

publisher

• Wiley  Publisher

published in

• European Journal of Inorganic Chemistry  Journal

keywords

• Multiple Bonds
• Polymers
• Rhenium
• Self-assembly
• Supramolecular Chemistry

Digital Object Identifier (DOI)

• 10.1002/ejic.200300268

start page

• 368

end page

• 375

volume

• 2004

issue

• 2

URL

• http://dx.doi.org/10.1002/ejic.200300268