Hexagonal layered materials composed of [M2(O2CCF3)4] (M = Ru and Rh) donors and TCNQ acceptors
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Delocalization throughout the extended layers of two-dimensional network polymers of the type [{M2(O2CCF3)4}2(TCNQ)3(C7H8)], which consist of Ru(II), Ru(II) and Rh(II), Rh(II) complexes coordinated to TCNQ molecules, is evident from the available structural (see picture for Ru analogue) and spectroscopic data. TCNQ = 7, 7, 8, 8-tetracyano-p-quinodimethane.