A porous Sm( iii ) coordination nanotube with hydrophobic and hydrophilic channels
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The π-π stacking interactions between tptz units from adjacent Sm(tptz)(HCOO)(3) coordination nanotubes leads to additional 1D channels (tptz = 2,4,6-tris(2-pyridyl)-s-triazine). The present compound is a rare case of a tubular porous material with both hydrophobic and hydrophilic channels. Permanent porosity was confirmed by N(2) adsorption isotherms.
author list (cited authors)
Lopez, N., Zhao, H., Zhao, D., Zhou, H., Riebenspies, J. P., & Dunbar, K. R.