Titanium(III) Member of the Family of Trigonal Building Blocks with Scorpionate and Cyanide Ligands Academic Article uri icon

abstract

  • The titanium(III) cyanide compound [Et4N][Tp*Ti(CN)3] ([Et4N] = tetraethylamonium; Tp* = 3,5-dimethyltrispyrazolylhydroborate) is reported, which exhibits a trigonally distorted geometry. Magnetic data and ab initio calculations verified that the molecule is an S = 1/2 paramagnet and that it exhibits significant temperature-independent paramagnetism.

author list (cited authors)

  • Brown, A., Saber, M., Van den Heuvel, W., Schulte, K., Soncini, A., & Dunbar, K. R.

publication date

  • January 1, 2017 11:11 AM