Titanium(III) Member of the Family of Trigonal Building Blocks with Scorpionate and Cyanide Ligands
- Additional Document Info
- View All
The titanium(III) cyanide compound [Et4N][Tp*Ti(CN)3] ([Et4N] = tetraethylamonium; Tp* = 3,5-dimethyltrispyrazolylhydroborate) is reported, which exhibits a trigonally distorted geometry. Magnetic data and ab initio calculations verified that the molecule is an S = 1/2 paramagnet and that it exhibits significant temperature-independent paramagnetism.
author list (cited authors)
Brown, A., Saber, M., Van den Heuvel, W., Schulte, K., Soncini, A., & Dunbar, K. R.