Titanium(III) Member of the Family of Trigonal Building Blocks with Scorpionate and Cyanide Ligands. Academic Article uri icon

abstract

  • The titanium(III) cyanide compound [Et4N][Tp*Ti(CN)3] ([Et4N] = tetraethylamonium; Tp* = 3,5-dimethyltrispyrazolylhydroborate) is reported, which exhibits a trigonally distorted geometry. Magnetic data and ab initio calculations verified that the molecule is an S = 1/2 paramagnet and that it exhibits significant temperature-independent paramagnetism.

published proceedings

  • Inorg Chem

altmetric score

  • 0.25

author list (cited authors)

  • Brown, A., Saber, M., Van den Heuvel, W., Schulte, K., Soncini, A., & Dunbar, K. R.

citation count

  • 8

complete list of authors

  • Brown, Andrew||Saber, Mohamed||Van den Heuvel, Willem||Schulte, Kelsey||Soncini, Alessandro||Dunbar, Kim R

publication date

  • February 2017