Systematic Study of Open-Shell Trigonal Pyramidal Transition-Metal Complexes with a Rigid-Ligand Scaffold. Academic Article uri icon

abstract

  • A family of distorted trigonal pyramidal transition-metal complexes [MII (N3 N)Li(THF)] (M=Mn, Fe, Co, Ni) have been studied as candidates for mononuclear single-molecule magnets. Magnetic anisotropy of the family depends on the electronic configuration of the central ion, with the Co analogue exhibiting pronounced SMM behavior.

published proceedings

  • Chemistry

author list (cited authors)

  • Pinkowicz, D., Birk, F. J., Magott, M., Schulte, K., & Dunbar, K. R.

citation count

  • 21

complete list of authors

  • Pinkowicz, Dawid||Birk, Francisco J||Magott, MichaƂ||Schulte, Kelsey||Dunbar, Kim R

publication date

  • March 2017

publisher