Systematic Study of Open‐Shell Trigonal Pyramidal Transition‐Metal Complexes with a Rigid‐Ligand Scaffold Academic Article uri icon

abstract

  • A family of distorted trigonal pyramidal transition-metal complexes [MII (N3 N)Li(THF)] (M=Mn, Fe, Co, Ni) have been studied as candidates for mononuclear single-molecule magnets. Magnetic anisotropy of the family depends on the electronic configuration of the central ion, with the Co analogue exhibiting pronounced SMM behavior.

author list (cited authors)

  • Pinkowicz, D., Birk, F. J., Magott, M., Schulte, K., & Dunbar, K. R.

citation count

  • 12

publication date

  • March 2017

publisher