Systematic Study of Open-Shell Trigonal Pyramidal Transition-Metal Complexes with a Rigid-Ligand Scaffold.

abstract

• A family of distorted trigonal pyramidal transition-metal complexes [MII (N3 N)Li(THF)] (M=Mn, Fe, Co, Ni) have been studied as candidates for mononuclear single-molecule magnets. Magnetic anisotropy of the family depends on the electronic configuration of the central ion, with the Co analogue exhibiting pronounced SMM behavior.

authors

• Dunbar, Kim

published proceedings

• Chemistry

author list (cited authors)

• Pinkowicz, D., Birk, F. J., Magott, M., Schulte, K., & Dunbar, K. R.

citation count

• 21

complete list of authors

• Pinkowicz, Dawid||Birk, Francisco J||Magott, Michał||Schulte, Kelsey||Dunbar, Kim R

publication date

• March 2017

publisher

• Wiley  Publisher

published in

• Chemistry - A European Journal  Journal

keywords

• Coordination Chemistry
• Magnetic Properties
• Nanomagnetism
• Single-molecule Magnets
• Trigonal Pyramidal Geometry

PubMed Central ID

• 28055144

Digital Object Identifier (DOI)

• 10.1002/chem.201605528

start page

• 3548

end page

• 3552

volume

• 23

issue

• 15

URL

• http://dx.doi.org/10.1002/chem.201605528