A Family of Octahedral Magnetic Molecules Based on [NbIV(CN)8]4. Academic Article

abstract

• A building block approach has been used to prepare a new family of hexanuclear magnetic molecules Mn4Nb2, Fe4Nb2, and Co4Nb2 of general formula {[MII(tmphen)2]4[NbIV(CN)8]2}solv (M = Mn, Fe, Co; tmphen = 3,4,7,8-tetramethyl-1,10-phenanthroline; solv = MeOH and/or H2O). Mn4Nb2 exhibits a magnetocaloric effect at temperatures close to 1.8 K, and Fe4Nb2 undergoes an incomplete gradual spin crossover and a photomagnetic response related to light-induced excited spin state trapping.

authors

• Dunbar, Kim

published proceedings

• Inorg Chem

author list (cited authors)

• Arczyski, M., Rams, M., Stanek, J., Fitta, M., Sieklucka, B., Dunbar, K. R., & Pinkowicz, D.

citation count

• 20

complete list of authors

• Arczyński, Mirosław||Rams, Michał||Stanek, Jan||Fitta, Magdalena||Sieklucka, Barbara||Dunbar, Kim R||Pinkowicz, Dawid

publication date

• April 2017

publisher

• American Chemical Society (ACS)  Publisher

published in

• Inorganic Chemistry  Journal

keywords

• Neurosciences
• Pediatric

PubMed Central ID

• 28322558

Digital Object Identifier (DOI)

• 10.1021/acs.inorgchem.6b03134

start page

• 4021

end page

• 4027

volume

• 56

issue

• 7

URL

• http://dx.doi.org/10.1021/acs.inorgchem.6b03134