Biosynthesis of thiamin thiazole: determination of the regiochemistry of the S/O acyl shift by using 1,4-dideoxy-D-xylulose-5-phosphate.
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Chatterjee, A., Han, X., McLafferty, F. W., & Begley, T. P.
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Chatterjee, Abhishek||Han, Xuemei||McLafferty, Fred W||Begley, Tadhg P
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Bacillus Subtilis
Catalysis
Magnetic Resonance Spectroscopy
Models, Chemical
Oxygen
Spectrometry, Mass, Electrospray Ionization
Sulfur
Thiamine
Thiazoles
Xylulose
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http://dx.doi.org/10.1002/anie.200504614