Infrared Quantum Cascade Laser Spectroscopy of Low Frequency Vibrations of Intermolecular Complexes
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abstract
Application of a QCL based spectrometer to cw supersonic slit jet expansions of CO and HX (X= F, Cl, CN, CCH) are reported. Spectroscopic analysis of fundamental, combination and hot bands of the CO stretching vibrations provide ro-vibrational parameters for low frequency intermolecular vibrations that can be incorporated in determination of morphed potentials for the respective dimers. 2011 IEEE.
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2011 International Conference on Infrared, Millimeter, and Terahertz Waves