The microwave spectrum and ground state dynamics of Kr-IH Academic Article

abstract

• The structure and ground state dynamics of the atom-diatom interaction between Kr and HI has been investigated by pulsed-nozzle Fourier-transform microwave spectroscopy. The ground state of 84Kr-IH is shown to have Rcm=4.0526(1) , =152.87(1) while Rcm=4.0195(1) , =158.85(1) for 84Kr-ID. The potential surface from an ab initio molecular orbital calculation was scaled and shifted to yield a non-linear least-squares fit of the rovibrational state energies to the experimental data. The ground state, Kr-IH isomeric structure is similar to Ar-IH but contrasts with other members of the homologous series Kr-HX (X=F, Cl and Br). 2000 Elsevier Science B.V.

authors

• Lucchese, Robert

published proceedings

• CHEMICAL PHYSICS LETTERS

author list (cited authors)

• McIntosh, A., Lin, P., Lucchese, R. R., Bevan, J. W., Brugh, D. J., & Suenram, R. D.

citation count

• 14

complete list of authors

• McIntosh, A||Lin, P||Lucchese, RR||Bevan, JW||Brugh, DJ||Suenram, RD

publication date

• November 2000

publisher

• Elsevier  Publisher

published in

• CHEMICAL PHYSICS LETTERS  Journal

keywords

• 34 Chemical Sciences
• 3406 Physical Chemistry
• 51 Physical Sciences
• 5102 Atomic, Molecular And Optical Physics

Digital Object Identifier (DOI)

• 10.1016/S0009-2614(00)01157-X

start page

• 95

end page

• 100

volume

• 331

issue

• 1

URL

• http://dx.doi.org/10.1016/s0009-2614(00)01157-x