Metallodithiolates as ligands in coordination, bioinorganic, and organometallic chemistry.
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A study was conducted to review the use of numerous MN2S2 complexes and their application as metallodithiolate ligands. The investigations focused on contiguous S-N-N-S tetradentate ligands that accommodated square planar binding and present the thiolate sulfurs in the cis-configuration that was conducive for them serving as bidentate S-donor ligands. The study also described bimetallic complexes evolving from MN2S2 metalloligands in combination with a transition metal acceptor bearing diatomic ligands as reporter groups of the electron-donating ability of the MN2S ligands.
author list (cited authors)
Denny, J. A., & Darensbourg, M. Y.
complete list of authors
Denny, Jason A||Darensbourg, Marcetta Y