Vibrational spectra, theoretical calculations, and structures for 1,3-disilacyclopent-4-ene and 1,3-disilacyclopentane and their tetrachloro derivatives Academic Article uri icon

abstract

  • The infrared and Raman spectra and theoretical calculations for 1,3-disilacyclopent-4-ene and 1,3-disilacyclopentane and their tetrachloro derivatives are reported. The calculated structures for the molecules have been found and the silicon-carbon bond where the carbon atom is olefinic was found to be shortened relative to SiH2-CH2-bonds. The agreement between observed and calculated spectra is very good. 2013 Elsevier B.V. All rights reserved.

published proceedings

  • JOURNAL OF MOLECULAR STRUCTURE

author list (cited authors)

  • Chun, H. J., Colegrove, L. F., & Laane, J.

citation count

  • 4

complete list of authors

  • Chun, Hye Jin||Colegrove, Lloyd F||Laane, Jaan

publication date

  • October 2013