Adsorption and removal of graphene dispersants. Academic Article uri icon


  • We demonstrate three different techniques (dialysis, vacuum filtration, and spray drying) for removal of dispersants from liquid-exfoliated graphene. We evaluate these techniques for elimination of dispersants from both the bulk liquid phase and from the graphene surface. Thermogravimetric analysis (TGA) confirms dispersant removal by these treatments. Vacuum filtration (driving by convective mass transfer) is the most effective method of dispersant removal, regardless of the type of dispersant, removing up to 95 wt.% of the polymeric dispersant with only 7.4 wt.% decrease in graphene content. Dialysis also removes a significant fraction (70 wt.% for polymeric dispersants) of un-adsorbed dispersants without disturbing the dispersion quality. Spray drying produces re-dispersible, crumpled powder samples and eliminates much of the unabsorbed dispersants. We also show that there is no rapid desorption of dispersants from the graphene surface. In addition, electrical conductivity measurements demonstrate conductivities one order of magnitude lower for graphene drop-cast films (where excess dispersants are present) than for vacuum filtered films, confirming poor inter-sheet connectivity when excess dispersants are present.

published proceedings

  • J Colloid Interface Sci

author list (cited authors)

  • Irin, F., Hansen, M. J., Bari, R., Parviz, D., Metzler, S. D., Bhattacharia, S. K., & Green, M. J.

citation count

  • 25

complete list of authors

  • Irin, Fahmida||Hansen, Matthew J||Bari, Rozana||Parviz, Dorsa||Metzler, Shane D||Bhattacharia, Sanjoy K||Green, Micah J

publication date

  • May 2015