KINETIC-ENERGY FUNCTIONS FOR THE RING-BENDING AND RING-TWISTING VIBRATIONS OF ASYMMETRICALLY SUBSTITUTED 6-MEMBERED RINGS Academic Article

abstract

• Vector models were developed for calculating the kinetic energy (reciprocal reduced mass) expressions for the ring-bending and single bond ring-twisting vibrations of six-membered rings with one double bond. These models are valid for asymmetrically substituted rings. A two-dimensional kinetic energy calculation was carried out and the twist-bend cross terms were also calculated. The reduced masses calculated for several oxygen-containing analogs of cyclohexene increase as the ring bends or twists. Kinetic energy expressions as functions of the vibrational coordinates were derived. 1989.

authors

• Laane, Jaan

published proceedings

• JOURNAL OF MOLECULAR SPECTROSCOPY

author list (cited authors)

• TECKLENBURG, M., & LAANE, J.

citation count

• 17

complete list of authors

• TECKLENBURG, MMJ||LAANE, J

publication date

• September 1989

publisher

• Elsevier  Publisher

published in

• Journal of Molecular Spectroscopy  Journal

Digital Object Identifier (DOI)

• 10.1016/0022-2852(89)90269-5

start page

• 65

end page

• 81

volume

• 137

issue

• 1

URL

• http://dx.doi.org/10.1016/0022-2852(89)90269-5